Interfacial profiles of mismatched lamellae in thin diblock copolymer films
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Directed assembly of lamellae forming block copolymer thin films near the order-disorder transition.
The impact of thin film confinement on the ordering of lamellae was investigated using symmetric poly(styrene-b-[isoprene-ran-epoxyisoprene]) diblock copolymers bound by nonpreferential wetting interfaces. The order-disorder transition temperature (TODT) and the occurrence of composition fluctuations in the disordered state are not significantly affected by two-dimensional confinement. Directed...
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Large-scale alignment of lamellae in thin films of diblock copolymers containing polyacrylonitrile and poly(n-butyl acrylate) was achieved by casting copolymer solution on a silicon substrate moved away at a constant speed from the casting nozzle (zone-casting). Grazing incidence small-angle X-ray scattering revealed that the lamellae, which were perpendicular to the substrate, were also aligne...
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The reorientation of lamellae and the dependence of the lamellar spacing, Dlam, on polymer volume fraction, ϕP, Dlam ∝ ϕP-β, in diblock copolymer thin films during solvent vapor annealing (SVA) are examined by combining white light interferometry (WLI) and grazing-incidence small-angle X-ray scattering (GISAXS). A thin film of lamellae-forming poly(styrene-b-butadiene) prepared by spin-coating ...
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Block copolymers have long been studied for their theories and applications especially in nanotechnology.1-5 They have periodic structures with 10-100 nm long microphase separated domains which can be controlled by the molecular weight and composition of the block copolymer. Regulating these two parameters, one can prepare thin films with different morphologies over large areas. The patterns fo...
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We examine the behavior of lamellar phases of charged/neutral diblock copolymer thin films containing mobile ions in the presence of an external electric field. We employ self-consistent field theory and focus on the aligning effect of the electric field on the lamellae. Of particular interest are the effects of the mobile ions on the critical field, the value required to reorient the lamellae ...
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